Solar rechargeable batteries (SRBs), as an emerging technology for harnessing solar energy, integrate the advantages of photochemical devices and redox batteries to synergistically couple dual-functional materials capable of both light harvesting and redox activity. This enables direct solar-to-electrochemical energy storage within a single
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Get a quoteHowever, capacity loss and low Coulombic efficiency resulting from polyiodide cross-over hinder the grid-level battery performance. Here, we develop colloidal chemistry for iodine-starch catholytes, endowing enlarged-sized active materials by strong chemisorption-induced colloidal aggregation.
For the I x− permeability under high temperature of 50 °C (Supplementary Figs. 42 and 43), the colloidal starch could strongly confine the polyiodides by forming a colloidal aggregation featuring low I x− permeability to impede the cross-over issue even at a severe condition of high temperature.
The colloidal IS-based Zn-IS FBs with polypropylene (PP) membranes as LPPM could deliver superior performance of cycling stability for 350 cycles at high current density. In addition, due to the strong chemisorption between starch and iodine redox, the as-developed colloidal IS systems remained stable.
The results could be attributed to the ultrasmall-sized colloidal starch that could cross the membrane to the anolyte and consequently stabilize the pH of the anolyte, hence endowing improved reversibility of the Zn anode.
The battery was assembled with carbon felts (2 cm × 2 cm × 0.46 cm) used as anodes, Zn metal (2 cm × 2 cm × 0.1 cm) and blank CF (2 cm × 2 cm × 0.46 cm) used as cathode, Celgard 3501 membrane and 20 mL of 2 M ZnCl 2 with/without 1 M starch used as electrolyte to flow past the two electrodes.
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